List of Publications
[86] Divalent Lanthanide Hydride Complexes
E. Stapf, A. Hinz*
Eur. J. Inorg. Chem., 2024, accepted.
[85] CO reduction by calcium and ytterbium hydride complexes with a bulky monodentate carbazolyl ligand
A. Hinz,* L. Winkler, X. Sun,
Chem. Commun. 2024, DOI 10.1039/D4CC03714F.
[84] Unconventional Insertions of Internal Alkynes into a Mixed-Valent Silaiminyl-Silylene
D. Jin, X. Sun, A. Hinz, P. W. Roesky*
Inorg. Chem., 2024, DOI 10.1021/acs.inorgchem.4c02384.
[83] De- and Rearomatisation of Pyridine in Silylene Chemistry
X. Sun, D. Jin, A. Hinz, P. W. Roesky*
Chem. Eur. J., 2024, DOI 10.1002/chem.202402456.
[82] Reactivities of phosphaalkynes towards diverse bis-silylenes
X. Sun, D. Jin, S. Maier, A. Hinz, P. W. Roesky*
Dalton Trans. 2024, DOI 10.1039/D4DT01367K.
[81] Hydride Abstraction From A BH4– Anion In A Carbazolyl Lanthanum Boranate
L. Winkler, E. Stapf, A. Hinz,*
Organometallics 2024, accepted article.
[80] Silylenes with a small chalcogenide substituent: Tuning frontier orbital energies from O to Te
M. P. Müller, A. Hinz,*
Angew. Chem. Int. Ed. 2024, accepted article.
A. Hinz,* M. Köckerling,
Z. Anorg. Allg. Chem. 2024, e202400025.
[78] Synthesis and reactivity of base-stabilised and base-free silaimidoyl bromides
P. Hädinger, M. P. Müller, A. Hinz,*
Inorg. Chem. 2024, 63, 4769–4776.
[77] Photolysis of phosphaketenyltetrylenes with a carbazolyl substituent
C. Li, A. Hinz,*
Chem. Asian J. 2023, DOI 10.1002/asia.202300698.
[76] Heteroatom-based Diradical(oid)s
A. Hinz,* J. Bresien,* F. Breher,* A. Schulz,*
Chem. Rev. 2023, 123, 10468-10526.
[75] Strain-driven, non-catalysed ring expansion of silicon heterocycles
M. P. Müller, A. Hinz,*
Chem. Eur. J. 2023, 29, e202302311.
[74] A Barium Complex of the Parent Silanide (SiH3–): Hydride Surrogate and Source of Silicon
X. Sun, A. Hinz,*
Inorg. Chem. 2023, 62, 0249-10255.
Q. Fan, X. Du, W. Yang, Q. Li, H. Sun, A. Hinz,* X. Li,*
Dalton Trans. 2023, 52, 6712–6721.
[72] Snapshots of Sequential Polyphosphide Rearrangement upon Metallatetrylene Addition
X. Sun, A. Hinz, S. Schulz, L. Zimmermann, M. Scheer, P. Roesky*
Chem. Sci. 2023, 14, 4769–4776.
[71] Efficient Fluorescence of Alkali Metal Carbazolides
M. Kaiser, M. P. Müller, F. Krätschmer, M. Rutschmann, A. Hinz,*
Inorg. Chem. Front. 2023, 2987–2994.
[70] Reversible Insertion of CO2 into a Bis(formazanate) Magnesium Complex
D. Jin, X. Sun, A. Hinz, P. Roesky*
CCS Chemistry 2023, 5, 1277–1284.
[69] Reactivity of Pt(0) bromosilylene complexes towards ethylene
P. Hädinger, A. Hinz,*
Dalton Trans. 2023, 52, 2214–2218.
[68] Control over Selectivity in Alkene Hydrosilylation Catalyzed by Cobalt(III) Hydride Complexes
H. Yang, A. Hinz,* Q. Fan, S. Xie, X. Qi, W. Huang, Q. Li, H. Sun, X. Li,*
Inorg. Chem. 2022, 61, 19710–19725.
[67] Forging a Cage into a Chain: Stepwise Transformation of P4 by Silylenes to a Si3P4 Motif
X. Sun, A. Hinz, P. Roesky,*
CCS Chemistry 2022, 4, 1843–1869.
[66] Functionalized Carbazolyl Hydro- and Allyl-Silanes
P. Hädinger, A. Hinz,*
Eur. J. Inorg. Chem. 2022, e202101112.
[65] Cyclopenta-fused polyaromatic hydrocarbons: synthesis and characterisation of a stable, carbon-centred helical radical
S. Herzog, A. Hinz,* F. Breher,* J. Podlech,*
Org. Biomol. Chem. 2022, 20, 2873–2880.
[64] Rare-earth metal complexes with redox-active formazanate ligands
D. Jin, X. Sun, A. Hinz, P. W. Roesky,*
Dalton Trans. 2022, 51, 5218–5226.
[63] Accessing Cationic α-Silylated and α-Germylated Phosphorus Ylides
F. Krämer, M. Radius, A. Hinz, M. E. A. Dilanas, F. Breher,*
Chem. Eur. J. 2022, e202103974.
[62] Stereoselective Activation of Small Molecules by a Stable Chiral Silene
X. Sun, A. Hinz, H. Kucher, M. T. Gamer, P. W. Roesky,*
Chem. Eur. J. 2022, e202201963.
[61] Complexes of 3d Metals with a Bulky Carbazolyl Ligand
M. Kaiser, L. Winkler, A. Hinz,*
Z. Anorg. Allg. Chem. 2022, e202200131.
[60] Stable bidentate silylene adducts of alkaline-earth amides
X. Sun, A. Hinz, M. T. Gamer, P. W. Roesky,*
Z. Anorg. Allg. Chem. 2022, e202200104.
[59] Synthesis of aryl cobalt and iron complexes and their catalytic activity on hydrosilylation of alkenes
W. Huang, J. Lu, Q. Fan, X. Li, A. Hinz,* H. Sun,*
New J. Chem. 2022, 7512–7521.
[58] Attempted reduction of a carbazolyl-diiodoalane
A. Hinz,* M. P. Müller,
Chem. Commun. 2021, 57, 12532–12535.
[57] Towards Heteroleptic Dicoordinate Cu(II) Complexes
M. Kaiser, J. Göttlicher, T. Vitova, A. Hinz,*
Chem. Eur. J. 2021, 7998–8002.
[56] Metalloradical Cations and Dications Based on Divinyldiphosphene and Divinyldiarsene Ligands
M. K. Sharma, D. Rottschäfer, B. Neumann, H.-G. Stammler, S. Danes, D. M. Andrada,* M. van Gastel, A. Hinz, R. S. Ghadwal,*
Chem. Eur. J. 2021, 5803–5809.
[55] On New Staudinger Type Reactions of Phosphorus Centered Biradicaloids, [P(μ‐NR)]2 (R = Ter, Hyp), with Ionic and Covalent Azides
A. Schulz,* A. Hinz, A. Rölke, A. Villinger, R. Wustrack,
Z. Anorg. Allg. Chem. 2021, 245–257.
[54] Tetravalent group 14 derivatives of a bulky aminocarbazole
J. Strecker, B. Pfeuffer, A. Hinz,*
Eur. J. Inorg. Chem. 2021, 658–663.
[53] A mono-substituted Si(II) cation – A crystalline "supersilylene"
A. Hinz,*
Angew. Chem. Int. Ed. 2020, 19065–19069.
[52] Isolation of singlet carbene derived 2-arsa-1,3-butadiene radical cations and dications
M. K. Sharma, S. Blomeyer, B. Neumann, H. G. Stammler, A. Hinz, M. Van Gastel, R. S. Ghadwal,*
Chem. Commun. 2020, 56, 3575–3578.
[51] Isolation of singlet carbene derived 2-phospha-1,3-butadienes and their sequential one-electron oxidation to radical cations and dications
M. K. Sharma, S. Blomeyer, T. Glodde, B. Neumann, H. G. Stammler, A. Hinz, M. Van Gastel, R. S. Ghadwal,*
Chem. Sci. 2020, 11, 1975–1984.
[50] Crystalline Divinyldiarsene Radical Cations and Dications
M. K. Sharma, S. Blomeyer, B. Neumann, H.-G. Stammler, M. van Gastel, A. Hinz, R. S. Ghadwal,*
Angew. Chem. Int. Ed. 2019, 17599–17603.
[49] Photoelectron spectroscopy and theoretical studies of PCSe−, AsCS−, AsCSe−, and NCSe−: Insights into the electronic structures of the whole family of ECX− (E = N, P, and As; X = O, S, and Se) anions
Q. Yuan, F. Tambornino, A. Hinz, W. T. Borden, J. M. Goicoechea,* B. Chen,* X.-B. Wang,*
Angew. Chem. Int. Ed. 2019, 15062–15068.
[48] Oxidative Coupling of Terminal Rhenium Pnictide Complexes
J. Abbenseth, M. Diefenbach, A. Hinz, L. Alig, C. Würtele, J. M. Goicoechea,* M. C. Holthausen,* S. Schneider,*
Angew. Chem. Int. Ed. 2019, 10966–10970.
[47] Synthesis and thermal decomposition of heavy tetrylenes bearing N‐Aminocarbazolyl substituents
A. Hinz,*
Chem. Eur. J. 2019, 7843–7846.
[46] Pseudo-one-coordinate Tetrylenium Salts Bearing a Bulky Carbazolyl Substituent
A. Hinz,*
Chem. Eur. J. 2019, 3267–3271.
[45] Diphosphene radical cations and dications with a π-conjugated C2P2C2-framework
M. K. Sharma, D. Rottschäfer, S. Blomeyer, B. Neumann, H.-G. Stammler, M. van Gastel, A. Hinz, R. S. Ghadwal,*
Chem. Commun. 2019, 10408–10411.
[44] Increasing steric demand through flexible bulk – primary phosphanes with 2,6-bis(benzhydryl) phenyl backbones
J. Bresien, J. M. Goicoechea, A. Hinz, M. T. Scharnhölz, A. Schulz,* T. Suhrbier, A. Villinger,
Dalton Trans. 2019, 3786–3794.
[43] Metastable phosphorus neutral monoradical: a key intermediate in the bicyclic cage formation
X. Chen, A. Hinz, J. R. Harmer,* Z. Li,*
Dalton Trans. 2019, 2549–2553.
[42] Square Planar Coordination of Silver in a η4‐Cyclobutadiene‐(η5‐C5H5)ReBr2 Complex Framework
S. Kleinschmidt, A. Hinz, A. Villinger, W. W. Seidel,*
Z. Anorg. Allg. Chem. 2018, 644, 1268–1273.
[41] Highlight: An Anionic Aluminium Nucleophile
A. Hinz,* F. Breher,*
Angew. Chem. 2018, 130, 8954–8956; Angew. Chem. Int. Ed. 2018, 57, 8818–8820.
[40] Intercepting a Transient Phosphino-Arsinidene
A. Hinz, M. M. Hansmann, G. Bertrand,* J. M. Goicoechea,*
Chem. Eur. J. 2018, 24, 9514–9519.
[39] A general synthesis of phosphorus- and arsenic-containing analogues of the thio- and seleno-cyanate anions
F. Tambornino, A. Hinz, R. Köppe, J. M. Goicoechea,*
Angew. Chem. 2018, 130, 8362–8366; Angew. Chem. Int. Ed. 2018, 57, 8230–8234.
[38] Limitations of Steric Bulk: Towards Phospha-Stannyne and Phospha-Germyne
A. Hinz,* J. M. Goicoechea,*
Chem. Eur. J. 2018, 24, 7358–7363.
[37] As-N and As-N-P Cage Compounds Generated by [2+2] Addition of Diazenes and Diphosphenes to Diarsadiazanediyls
J. Bresien, A. Hinz, A. Schulz,* A. Villinger,
Eur. J. Inorg. Chem. 2018, 1679–1682.
[36] Biradicaloid and Zwitterion Reactivity of Dicarbondiphosphide Stabilized with N-Heterocyclic Carbenes
Z. Li,* Y. Hou, Y. Li, A. Hinz,* X. Chen,*
Chem. Eur. J. 2018, 24, 4849–4855. Highlighted with a Cover Feature.
[35] An isolable phosphaethynolato-borane and its reactivity
D. W. N. Wilson, A. Hinz, J. M. Goicoechea,*
Angew. Chem. 2018, 130, 2210–2215; Angew. Chem. Int. Ed. 2018, 57, 2188–2193.
[34] Synthesis and reactivity of nickel-stabilised µ2:η2,η2-P2, As2 and PAs units
G. Hierlmeier, A. Hinz, R. Wolf,* J. M. Goicoechea,*
Angew. Chem. 2018, 130, 439–444; Angew. Chem. Int. Ed. 2018, 57, 431–436.
[33] L3C3P3: Tricarbontriphosphide Cage Radicals and Cations Stabilized by Cyclic (alkyl)(amino)carbenes
Z. Li, Y. Hou, Y. Li, A. Hinz, J. R. Harmer,* C.-Y. Su,* G. Bertrand, H. Grützmacher,*
Angew. Chem. 2018, 130, 204–208; Angew. Chem. Int. Ed. 2018, 57, 198–202.
[32] The heterocubane [TerSnAs]4
A. Hinz,* J. M. Goicoechea,*
Dalton Trans. 2018, 8879–8883.
[31] Trapping of Transient, Heavy Pnictogen-Centred Biradicals
J. Bresien, A. Hinz, A. Schulz,* A. Villinger,
Dalton Trans. 2018, 47, 4433–4436.
[30] On the Borderline Between Discrete Complex Ions and Extended Structures: An Unprecedented Large Undecanuclear Azido-cuprate(II) Anion in Crystals of (PPN)2[Cu11(N3)24(C2H5OH)2]
A. Hinz, M. Köckerling,*
ChemistrySelect 2017, 2, 9654–9657.
[29] Dichloro-cycloazatriphosphane – the missing link between N2P2 and P4 ring systems in the systematic development of NP chemistry
J. Bresien, A. Hinz, A. Schulz,* T. Suhrbier, M. Thomas, A. Villinger,
Chem. Eur. J. 2017, 23, 14738–14742.
[28] HPCO – A Phosphorus-Containing Analogue of Isocyanic Acid
A. Hinz, R. Labbow, C. Rennick, A. Schulz, J. M. Goicoechea,*
Angew. Chem. 2017, 129, 3969–3973; Angew. Chem. Int. Ed. 2017, 56, 3911–3915.
[27] Synthesis, Properties, and Structures of Low-melting Tetraisocyanato-cobaltate(II)-based Ionic Liquids
T. Peppel, A. Hinz, P. Thiele, M. Geppert-Rybczyńska, J. K. Lehmann, M. Köckerling,*
Eur. J. Inorg. Chem. 2017, 2017, 885–893.
[26] N-Heterocyclic Carbene-Stabilised Arsinidene (AsH)
A. Doddi, M. Weinhart, A. Hinz, D. Bockfeld, J. M. Goicoechea, M. Scheer,* M. Tamm,*
Chem. Commun. 2017, 53, 6069–6072.
[25] A Monoanionic Arsenide Source. Decarbonylation of the 2-Arsaethynolate Anion on Reaction with Bulky Stannylenes
A. Hinz, J. M. Goicoechea,*
Angew. Chem. 2016, 128, 15741–15746; Angew. Chem. Int. Ed. 2016, 55, 15515–15519.
[24] Metal-free Activation of Hydrogen, Carbon Dioxide and Ammonia by Open Shell Singlet Biradicaloid [P(µ-NTer)]2
A. Hinz, A. Schulz,* A. Villinger,
Angew. Chem. 2016, 128, 12402–12406; Angew. Chem. Int. Ed. 2016, 55, 12214–12218.
[23] Synthesis Of A Molecule With Four Different Adjacent Pnictogens
A. Hinz, A. Schulz,* A. Villinger,
Chem. Eur. J. 2016, 22, 12266–12269. Highlighted in C&EN 2016, 94 (30), 11.
[22] Synthesis of a Silylated Phosphorus Biradicaloid and Its Utilization in the Activation of Small Molecules
A. Hinz, A. Schulz,* A. Villinger,
Eur. J. Inorg. Chem. 2016, 22, 3611–3619.
[21] Minimalistic ditopic ligands: S,N-donor-substituted alkyne as effective intermetallic conjugation linker
J. Rüger, C. Timmermann, A. Villinger, A. Hinz, D. Hollmann, W. W. Seidel,*
Chem. Eur. J. 2016, 22, 11191–11195.
[20] The 2-arsaethynolate anion. Synthesis and reactivity towards heteroallenes
A. Hinz, J. Goicoechea,*
Angew. Chem. 2016, 128, 8678–8683; Angew. Chem. Int. Ed. 2016, 55, 8536–8541. Frontispiece in Angew. Chem./Angew. Chem. Int. Ed. 2016. Highlighted in C&EN 2016, 94 (18), 11, and in Nachrichten aus der Chemie 2016, 64 (10), 943.
[19] Synthesis of Heavy Dipnicta-diphosphacyclobutanes [ClE(µ-PTer)]2
A. Hinz, A. Schulz,* A. Villinger,
Inorg. Chem. 2016, 55, 3692–3699.
[18] Activation of Small Molecules by Biradicaloids
A. Hinz, A. Schulz,*
Phosphorus Sulfur Silicon Relat. Elem. 2016, 191, 578–581.
[17] On the Behaviour of Biradicaloid [P(µ-NTer)]2 Towards Lewis Acids and Bases
A. Hinz, A. Schulz,* A. Villinger,
Chem. Commun. 2016, 52, 6328–6331.
[16] Reduction of dichloro(diaza-phospha)stibanes – isolation of a donor-stabilized distibenium dication
A. Hinz, J. Rothe, A. Schulz,* A. Villinger,
Dalton Trans. 2016, 45, 6044–6052.
[15] A Zwitterionic and a Biradicaloid Cyclopentane Derivative
A. Hinz, A. Schulz,* A. Villinger,
Chem. Sci. 2016, 7, 745–751.
[14] Synthesis and Structure of Tritylium Salts
A. Hinz, R. Labbow, F. Reiß, A. Schulz,* K. Sievert, A. Villinger,
Struct. Chem. 2015, 26, 1641–1650.
[13] Tunable Formation of Cyclopentane-1,3-diyls by 1,1-Insertion of Isonitriles into Diphosphadiazanediyl
A. Hinz, A. Schulz,* A. Villinger,
J. Am. Chem. Soc. 2015, 137, 9953–9962.
[12] Accessing heavy allyl-analogous [(TerN)2E]– (E = Sb, Bi) salts and their reactivity towards ECl3
A. Hinz, A. Schulz,* A. Villinger,
Chem. Commun. 2015, 51, 11437–11440.
[11] A New Mixed-Valent Copper Cyanido complex and a new Copper(II) Acetato complex, prepared with an Ionic Liquid
A. Hinz, M. Köckerling,*
Z. Anorg. Allg. Chem. 2015, 641, 1347–1351.
[10] Cyclic Group 15 Radical Cations
A. Brückner, A. Hinz, J. B. Priebe, A. Schulz,* A. Villinger,
Angew. Chem. 2015, 127, 7534–7538; Angew. Chem. Int. Ed. 2015, 54, 7426–7430.
[9] Cyclo-Pnicta-triazanes: Biradicaloids – or Zwitterions?
A. Hinz, A. Schulz,* A. Villinger, J.-M. Wolter,
J. Am. Chem. Soc. 2015, 137, 3975–3980.
[8] Spontaneous Formation of an η4-Ethylene Bis(carbene) Ligand by Alkyne Coupling at Re(III)
S. Kleinschmidt, D. Schallenberg, K. Helmdach, A. Hinz, A. Villinger, W. W. Seidel,*
Organometallics 2015, 34, 1091–1097.
[7] Stable Heterocyclopentane-1,3-diyls
A. Hinz, A. Schulz,* A. Villinger,
Angew. Chem. 2015, 127, 2815–2819; Angew. Chem. Int. Ed. 2015, 54, 2776–2779.
[6] P-P sigma-Bond Activation by Gold(I) Coordination
A. Hinz, A. Schulz,* A. Villinger,
Chem. Commun. 2015, 51, 1363–1366.
[5] A Mixed Arsenic-Phosphorus Centered Biradicaloid
A. Hinz, A. Schulz,* A. Villinger,
Angew. Chem. 2014, 127, 678–682; Angew. Chem. Int. Ed. 2014, 54, 668–672.
[4] Activation of Small Molecules by Phosphorus Biradicaloids
A. Hinz, R. Kuzora, U. Rosenthal, A. Schulz,* A. Villinger,
Chem. Eur. J. 2014, 2, 14659–14673.
[3] A New Class of Azadipnictiridines Generated by an Unusual Rearrangement Reaction
A. Hinz, A. Schulz,* W. W. Seidel, A. Villinger,
Inorg. Chem. 2014, 53, 11682–11690.
[2] New P-N cage compounds generated by small-molecule activation
A. Hinz, A. Schulz,* A. Villinger,
Chem. Eur. J. 2014, 20, 3913–3916.
[1] Salts with the [NiBr3(L)]– complex anion (L = 1-methylimidazole, 1-methylbenzimidazole, quinoline, and triphenylphosphane) and low melting points: A comparative study
T. Peppel, A. Hinz, M. Köckerling,*
Polyhedron 2013, 52, 482–490.