List of Publications
[67] Forging a Cage into a Chain: Stepwise Transformation of P4 by Silylenes to a Si3P4 Motif
X. Sun, A. Hinz, P. Roesky,
CCS Chemistry 2022, 4, 1843–1869.
[66] Functionalized Carbazolyl Hydro- and Allyl-Silanes
P. Hädinger, A. Hinz,
Eur. J. Inorg. Chem. 2022, DOI 10.1002/ejic.202101112.
[65] Cyclopenta-fused polyaromatic hydrocarbons: synthesis and characterisation of a stable, carbon-centred helical radical
S. Herzog, A. Hinz, F. Breher, J. Podlech,
Org. Biomol. Chem. 2022, 20, 2873–2880.
[64] Rare-earth metal complexes with redox-active formazanate ligands
D. Jin, X. Sun, A. Hinz, P. W. Roesky,
Dalton Trans. 2022, 51, 5218–5226.
[63] Accessing Cationic α-Silylated and α-Germylated Phosphorus Ylides
F. Krämer, M. Radius, A. Hinz, M. E. A. Dilanas, F. Breher,
Chem. Eur. J. 2022, DOI 10.1002/chem.202103974.
[62] Stereoselective Activation of Small Molecules by a Stable Chiral Silene
X. Sun, A. Hinz, H. Kucher, M. T. Gamer, P. W. Roesky,
Chem. Eur. J. 2022, DOI 10.1002/chem.202201963.
[61] Complexes of 3d Metals with a Bulky Carbazolyl Ligand
M. Kaiser, L. Winkler, A. Hinz,
Z. Anorg. Allg. Chem. 2022, DOI 10.1002/zaac.202200131.
[60] Stable bidentate silylene adducts of alkaline-earth amides
X. Sun, A. Hinz, M. T. Gamer, P. W. Roesky,
Z. Anorg. Allg. Chem. 2022, DOI 10.1002/zaac.202200104.
[59] Synthesis of aryl cobalt and iron complexes and their catalytic activity on hydrosilylation of alkenes
W. Huang, J. Lu, Q. Fan, X. Li, A. Hinz, H. Sun,
New J. Chem. 2022, 7512–7521.
[58] Attempted reduction of a carbazolyl-diiodoalane
A. Hinz, M. P. Müller,
Chem. Commun. 2021, 57, 12532–12535.
[57] Towards Heteroleptic Dicoordinate Cu(II) Complexes
M. Kaiser, J. Göttlicher, T. Vitova, A. Hinz,
Chem. Eur. J. 2021, 7998–8002.
[56] Metalloradical Cations and Dications Based on Divinyldiphosphene and Divinyldiarsene Ligands
M. K. Sharma, D. Rottschäfer, B. Neumann, H.-G. Stammler, S. Danes, D. M. Andrada, M. van Gastel, A. Hinz, R. S. Ghadwal,
Chem. Eur. J. 2021, 5803–5809.
[55] On New Staudinger Type Reactions of Phosphorus Centered Biradicaloids, [P(μ‐NR)]2 (R = Ter, Hyp), with Ionic and Covalent Azides
A. Schulz, A. Hinz, A. Rölke, A. Villinger, R. Wustrack,
Z. Anorg. Allg. Chem. 2021, 245–257.
[54] Tetravalent group 14 derivatives of a bulky aminocarbazole
J. Strecker, B. Pfeuffer, A. Hinz,
Eur. J. Inorg. Chem. 2021, 658-663.
[53] A mono-substituted Si(II) cation - A crystalline "supersilylene"
A. Hinz,
Angew. Chem. Int. Ed. 2020, 19065–19069.
[52] Isolation of singlet carbene derived 2-arsa-1,3-butadiene radical cations and dications
M. K. Sharma, S. Blomeyer, B. Neumann, H. G. Stammler, A. Hinz, M. Van Gastel, R. S. Ghadwal,
Chem. Commun. 2020, 56, 3575–3578.
[51] Isolation of singlet carbene derived 2-phospha-1,3-butadienes and their sequential one-electron oxidation to radical cations and dications
M. K. Sharma, S. Blomeyer, T. Glodde, B. Neumann, H. G. Stammler, A. Hinz, M. Van Gastel, R. S. Ghadwal,
Chem. Sci. 2020, 11, 1975–1984.
[50] Crystalline Divinyldiarsene Radical Cations and Dications
M. K. Sharma, S. Blomeyer, B. Neumann, H.-G. Stammler, M. van Gastel, A. Hinz, R. S. Ghadwal,
Angew. Chem. Int. Ed. 2019, 17599–17603.
[49] Photoelectron spectroscopy and theoretical studies of PCSe−, AsCS−, AsCSe−, and NCSe−: Insights into the electronic structures of the whole family of ECX− (E = N, P, and As; X = O, S, and Se) anions
Q. Yuan, F. Tambornino, A. Hinz, W. T. Borden, J. M. Goicoechea, B. Chen, X.-B. Wang,
Angew. Chem. Int. Ed. 2019, 15062–15068.
[48] Oxidative Coupling of Terminal Rhenium Pnictide Complexes
J. Abbenseth, M. Diefenbach, A. Hinz, L. Alig, C. Würtele, J. M. Goicoechea, M. C. Holthausen, S. Schneider,
Angew. Chem. Int. Ed. 2019, 10966–10970.
[47] Synthesis and thermal decomposition of heavy tetrylenes bearing N‐Aminocarbazolyl substituents
A. Hinz,
Chem. Eur. J. 2019, 7843–7846.
[46] Pseudo-one-coordinate Tetrylenium Salts Bearing a Bulky Carbazolyl Substituent
A. Hinz,
Chem. Eur. J. 2019, 3267–3271.
[45] Diphosphene radical cations and dications with a π-conjugated C2P2C2-framework
M. K. Sharma, D. Rottschäfer, S. Blomeyer, B. Neumann, H.-G. Stammler, M. van Gastel, A. Hinz, R. S. Ghadwal,
Chem. Commun. 2019, 10408–10411.
[44] Increasing steric demand through flexible bulk – primary phosphanes with 2,6-bis(benzhydryl) phenyl backbones
J. Bresien, J. M. Goicoechea, A. Hinz, M. T. Scharnhölz, A. Schulz, T. Suhrbier, A. Villinger,
Dalton Trans. 2019, 3786–3794.
[43] Metastable phosphorus neutral monoradical: a key intermediate in the bicyclic cage formation
X. Chen, A. Hinz, J. R. Harmer, Z. Li,
Dalton Trans. 2019, 2549–2553.
[42] Square Planar Coordination of Silver in a η4‐Cyclobutadiene‐(η5‐C5H5)ReBr2 Complex Framework
S. Kleinschmidt, A. Hinz, A. Villinger, W. W. Seidel,
Z. Anorg. Allg. Chem. 2018, 644, 1268–1273.
[41] Highlight: An Anionic Aluminium Nucleophile
A. Hinz, F. Breher,
Angew. Chem. 2018, 130, 8954–8956; Angew. Chem. Int. Ed. 2018, 57, 8818–8820.
[40] Intercepting a Transient Phosphino-Arsinidene
A. Hinz, M. M. Hansmann, G. Bertrand, J. M. Goicoechea,
Chem. Eur. J. 2018, 24, 9514–9519.
[39] A general synthesis of phosphorus- and arsenic-containing analogues of the thio- and seleno-cyanate anions
F. Tambornino, A. Hinz, R. Köppe, J. M. Goicoechea,
Angew. Chem. 2018, 130, 8362–8366; Angew. Chem. Int. Ed. 2018, 57, 8230–8234.
[38] Limitations of Steric Bulk: Towards Phospha-Stannyne and Phospha-Germyne
A. Hinz, J. M. Goicoechea,
Chem. Eur. J. 2018, 24, 7358–7363.
[37] As-N and As-N-P Cage Compounds Generated by [2+2] Addition of Diazenes and Diphosphenes to Diarsadiazanediyls
J. Bresien, A. Hinz, A. Schulz, A. Villinger,
Eur. J. Inorg. Chem. 2018, 1679–1682.
[36] Biradicaloid and Zwitterion Reactivity of Dicarbondiphosphide Stabilized with N-Heterocyclic Carbenes
Z. Li, Y. Hou, Y. Li, A. Hinz, X. Chen,
Chem. Eur. J. 2018, 24, 4849–4855. Highlighted with a Cover Feature.
[35] An isolable phosphaethynolato-borane and its reactivity
D. W. N. Wilson, A. Hinz, J. M. Goicoechea,
Angew. Chem. 2018, 130, 2210–2215; Angew. Chem. Int. Ed. 2018, 57, 2188–2193.
[34] Synthesis and reactivity of nickel-stabilised µ2:η2,η2-P2, As2 and PAs units
G. Hierlmeier, A. Hinz, R. Wolf, J. M. Goicoechea,
Angew. Chem. 2018, 130, 439–444; Angew. Chem. Int. Ed. 2018, 57, 431–436.
[33] L3C3P3: Tricarbontriphosphide Cage Radicals and Cations Stabilized by Cyclic (alkyl)(amino)carbenes
Z. Li, Y. Hou, Y. Li, A. Hinz, J. R. Harmer, C.-Y. Su, G. Bertrand, H. Grützmacher,
Angew. Chem. 2018, 130, 204–208; Angew. Chem. Int. Ed. 2018, 57, 198–202.
[32] The heterocubane [TerSnAs]4
A. Hinz, J. M. Goicoechea,
Dalton Trans. 2018, 8879–8883.
[31] Trapping of Transient, Heavy Pnictogen-Centred Biradicals
J. Bresien, A. Hinz, A. Schulz, A. Villinger,
Dalton Trans. 2018, 47, 4433–4436.
[30] On the Borderline Between Discrete Complex Ions and Extended Structures: An Unprecedented Large Undecanuclear Azido-cuprate(II) Anion in Crystals of (PPN)2[Cu11(N3)24(C2H5OH)2]
A. Hinz, M. Köckerling,
ChemistrySelect 2017, 2, 9654–9657.
[29] Dichloro-cycloazatriphosphane – the missing link between N2P2 and P4 ring systems in the systematic development of NP chemistry
J. Bresien, A. Hinz, A. Schulz, T. Suhrbier, M. Thomas, A. Villinger,
Chem. Eur. J. 2017, 23, 14738–14742.
[28] HPCO – A Phosphorus-Containing Analogue of Isocyanic Acid
A. Hinz, R. Labbow, C. Rennick, A. Schulz, J. M. Goicoechea,
Angew. Chem. 2017, 129, 3969–3973; Angew. Chem. Int. Ed. 2017, 56, 3911–3915.
[27] Synthesis, Properties, and Structures of Low-melting Tetraisocyanato-cobaltate(II)-based Ionic Liquids
T. Peppel, A. Hinz, P. Thiele, M. Geppert-Rybczyńska, J. K. Lehmann, M. Köckerling,
Eur. J. Inorg. Chem. 2017, 2017, 885–893.
[26] N-Heterocyclic Carbene-Stabilised Arsinidene (AsH)
A. Doddi, M. Weinhart, A. Hinz, D. Bockfeld, J. M. Goicoechea, M. Scheer, M. Tamm,
Chem. Commun. 2017, 53, 6069–6072.
[25] A Monoanionic Arsenide Source. Decarbonylation of the 2-Arsaethynolate Anion on Reaction with Bulky Stannylenes
A. Hinz, J. M. Goicoechea,
Angew. Chem. 2016, 128, 15741–15746; Angew. Chem. Int. Ed. 2016, 55, 15515–15519.
[24] Metal-free Activation of Hydrogen, Carbon Dioxide and Ammonia by Open Shell Singlet Biradicaloid [P(µ-NTer)]2
A. Hinz, A. Schulz, A. Villinger,
Angew. Chem. 2016, 128, 12402–12406; Angew. Chem. Int. Ed. 2016, 55, 12214–12218.
[23] Synthesis Of A Molecule With Four Different Adjacent Pnictogens
A. Hinz, A. Schulz, A. Villinger,
Chem. Eur. J. 2016, 22, 12266–12269. Highlighted in C&EN 2016, 94 (30), 11.
[22] Synthesis of a Silylated Phosphorus Biradicaloid and Its Utilization in the Activation of Small Molecules
A. Hinz, A. Schulz, A. Villinger,
Eur. J. Inorg. Chem. 2016, 22, 3611–3619.
[21] Minimalistic ditopic ligands: S,N-donor-substituted alkyne as effective intermetallic conjugation linker
W. W. Seidel, J. Rüger, C. Timmermann, A. Villinger, A. Hinz, D. Hollmann,
Chem. Eur. J. 2016, 22, 11191–11195.
[20] The 2-arsaethynolate anion. Synthesis and reactivity towards heteroallenes
A. Hinz, J. Goicoechea,
Angew. Chem. 2016, 128, 8678–8683; Angew. Chem. Int. Ed. 2016, 55, 8536–8541. Frontispiece in Angew. Chem./Angew. Chem. Int. Ed. 2016. Highlighted in C&EN 2016, 94 (18), 11, and in Nachrichten aus der Chemie 2016, 64 (10), 943.
[19] Synthesis of Heavy Dipnicta-diphosphacyclobutanes [ClE(µ-PTer)]2
A. Hinz, A. Schulz, A. Villinger,
Inorg. Chem. 2016, 55, 3692–3699.
[18] Activation of Small Molecules by Biradicaloids
A. Hinz, A. Schulz,
Phosphorus Sulfur Silicon Relat. Elem. 2016, 191, 578–581.
[17] On the Behaviour of Biradicaloid [P(µ-NTer)]2 Towards Lewis Acids and Bases
A. Hinz, A. Schulz, A. Villinger,
Chem. Commun. 2016, 52, 6328–6331.
[16] Reduction of dichloro(diaza-phospha)stibanes – isolation of a donor-stabilized distibenium dication
A. Hinz, J. Rothe, A. Schulz, A. Villinger,
Dalton Trans. 2016, 45, 6044–6052.
[15] A Zwitterionic and a Biradicaloid Cyclopentane Derivative
A. Hinz, A. Schulz, A. Villinger,
Chem. Sci. 2016, 7, 745–751.
[14] Synthesis and Structure of Tritylium Salts
A. Hinz, R. Labbow, F. Reiß, A. Schulz, K. Sievert, A. Villinger,
Struct. Chem. 2015, 26, 1641–1650.
[13] Tunable Formation of Cyclopentane-1,3-diyls by 1,1-Insertion of Isonitriles into Diphosphadiazanediyl
A. Hinz, A. Schulz, A. Villinger,
J. Am. Chem. Soc. 2015, 137, 9953–9962.
[12] Accessing heavy allyl-analogous [(TerN)2E]– (E = Sb, Bi) salts and their reactivity towards ECl3
A. Hinz, A. Schulz, A. Villinger,
Chem. Commun. 2015, 51, 11437–11440.
[11] A New Mixed-Valent Copper Cyanido complex and a new Copper(II) Acetato complex, prepared with an Ionic Liquid
A. Hinz, M. Köckerling,
Z. Anorg. Allg. Chem. 2015, 641, 1347–1351.
[10] Cyclic Group 15 Radical Cations
A. Brückner, A. Hinz, J. B. Priebe, A. Schulz, A. Villinger,
Angew. Chem. 2015, 127, 7534–7538; Angew. Chem. Int. Ed. 2015, 54, 7426–7430.
[9] Cyclo-Pnicta-triazanes: Biradicaloids – or Zwitterions?
A. Hinz, A. Schulz, A. Villinger, J.-M. Wolter,
J. Am. Chem. Soc. 2015, 137, 3975–3980.
[8] Spontaneous Formation of an η4-Ethylene Bis(carbene) Ligand by Alkyne Coupling at Re(III)
S. Kleinschmidt, D. Schallenberg, K. Helmdach, A. Hinz, A. Villinger, W. W. Seidel,
Organometallics 2015, 34, 1091–1097.
[7] Stable Heterocyclopentane-1,3-diyls
A. Hinz, A. Schulz, A. Villinger,
Angew. Chem. 2015, 127, 2815–2819; Angew. Chem. Int. Ed. 2015, 54, 2776–2779.
[6] P-P sigma-Bond Activation by Gold(I) Coordination
A. Hinz, A. Schulz, A. Villinger,
Chem. Commun. 2015, 51, 1363–1366.
[5] A Mixed Arsenic-Phosphorus Centered Biradicaloid
A. Hinz, A. Schulz, A. Villinger,
Angew. Chem. 2014, 127, 678–682; Angew. Chem. Int. Ed. 2014, 54, 668–672.
[4] Activation of Small Molecules by Phosphorus Biradicaloids
A. Hinz, R. Kuzora, U. Rosenthal, A. Schulz, A. Villinger,
Chem. Eur. J. 2014, 2, 14659–14673.
[3] A New Class of Azadipnictiridines Generated by an Unusual Rearrangement Reaction
A. Hinz, A. Schulz, W. W. Seidel, A. Villinger,
Inorg. Chem. 2014, 53, 11682–11690.
[2] New P-N cage compounds generated by small-molecule activation
A. Hinz, A. Schulz, A. Villinger,
Chem. Eur. J. 2014, 20, 3913–3916.
[1] Salts with the [NiBr3(L)]– complex anion (L = 1-methylimidazole, 1-methylbenzimidazole, quinoline, and triphenylphosphane) and low melting points: A comparative study
T. Peppel, A. Hinz, M. Köckerling,
Polyhedron 2013, 52, 482–490.
Monographs
[2] Untersuchungen zu Gruppe-15-Biradikaloiden
A. Hinz, 2015, Dissertation, Universität Rostock.
[1] Reaktionen von Übergangsmetallsalzen mit ionischen Flüssigkeiten
A. Hinz, 2012, Diplomarbeit, Universität Rostock.
Book Chapters
[1] Germanium-Containing Radicals
A. Hinz, F. Breher, in Organogermanium Compounds: Theory, Experiment, and Applications; Ed. Vladimir Lee; 2021, John Wiley and Sons, Inc., New York.